排序方式： 共有19条查询结果，搜索用时 578 毫秒
1.
H. Yang R. M. Hazen L. W. Finger C. T. Prewitt R. T. Downs 《Physics and Chemistry of Minerals》1997,25(1):39-47
The unit-cell dimensions and crystal structure of sillimanite at various pressures up to 5.29 GPa have been refined from single-crystal X-ray diffraction data. As pressure increases, a and b decrease linearly, whereas c decreases nonlinearly with a slightly positive curvature. The axial compression ratios at room pressure are βa:βb:βc=1.22:1.63:1.00. Sillimanite exhibits the least compressibility along c, but the least thermal expansivity along a (Skinner et al. 1961; Winter and Ghose 1979). The bulk modulus of sillimanite is 171(1) GPa with K′=4 (3), larger than that of andalusite (151 GPa), but smaller than that of kyanite (193 GPa). The bulk moduli of the [Al1O6], [Al2O4], and [SiO4] polyhedra are 162(8), 269(33), and 367(89) GPa, respectively. Comparison of high-pressure data for Al2SiO5 polymorphs reveals that the [SiO4] tetrahedra are the most rigid units in all these polymorphic structures, whereas the [AlO6] octahedra are most compressible. Furthermore, [AlO6] octahedral compressibilities decrease from kyanite to sillimanite, to andalusite, the same order as their bulk moduli, suggesting that [AlO6] octahedra control the compression of the Al2SiO5 polymorphs. The compression of the [Al1O6] octahedron in sillimanite is anisotropic with the longest Al1-OD bond shortening by ～1.9% between room pressure and 5.29 GPa and the shortest Al1-OB bond by only 0.3%. The compression anisotropy of sillimanite is primarily a consequence of its topological anisotropy, coupled with the compression anisotropy of the Al-O bonds within the [Al1O6] octahedron. 相似文献
2.
Jaidong Ko Nancy E. Brown Alexandra Navrotsky Charles T. Prewitt Tibor Gasparik 《Physics and Chemistry of Minerals》1989,16(8):727-733
The phase boundary between MnTiO3 I (ilmenite structure) and MnTiO3 II (lithium niobate structure) has been determined by analysis of quench products from reversal experiments in a cubic anvil
apparatus at 1073–1673 K and 43–75 kbar using mixtures of MnTiO3 I and II as starting materials. Tight brackets of the boundary give P(kbar)=121.2−0.045 T(K). Thermodynamic analysis of this boundary gives ΔHo=5300±1000 J·mol−1, ΔSo = 1.98 ±1J·K−1· mol−1. The enthalpy of transformation obtained directly by transposed-temperature-drop calorimetry is 8359 ±2575 J·mol−1. Possible topologies of the phase relations among the ilmenite, lithium niobate, and perovskite polymorphs are constrained
using the above data and the observed (reversible with hysteresis) transformation of II to III at 298 K and 20–30 kbar (Ross
et al. 1989). The observed II–III transition is likely to lie on a metastable extension of the II–III boundary into the ilmenite
field. However the reversed I–II boundary, with its negative dP/ dT does represent stable equilibrium between ilmenite and lithium niobate, as opposed to the lithium niobate being a quench
product of perovskite. We suggest a topology in which the perovskite occurs stably at low T and high P with a triple point (I, II, III) at or below 1073 K near 70 kbar. The I–II boundary would have a negative P-T slope while the II–III and I–III boundaries would be positive, implying that entropy decreases in the order lithium niobate,
ilmenite, perovskite. The inferred positive slope of the ilmenite-perovskite transition in MnTiO3 is different from the negative slopes in silicates and germanates. These thermochemical parameters are discussed in terms
of crystal structure and lattice vibrations. 相似文献
3.
颅脑外伤分类的CT特征 总被引：2，自引：2，他引：0
本文目的在于进一步提高对多种颅脑损伤的认识水平。所用材料和方法为本组１３５例,男９８例,女３７例,年龄４＿７７岁,平均年龄２４．８３岁。车祸伤９３例,跌伤２８例,击伤１４伤,１０１例有昏迷史,全部病例均作头颅ＣＴ轴位平扫。从相互伴发的多种颅脑损伤的角度,详细分析了它们的ＣＴ表现。结果得到了１３５例中,有多种类型颅脑损伤１３３例,单纯脑挫裂伤２例;硬膜外血肿１０４例,合并同一部位骨折７５例,占７２．１５％,合并脑挫裂伤占７０．３７％;硬膜下血肿２０例,位于外力对冲部位１５例．占７５％,合并脑挫伤裂伤１２例,其中１１例邻近硬膜下血肿;外伤后２小时内ＣＴ检查,并于外伤后４小时至５天内ＣＴ复查４７例,发现病变进展３８例,占８０．９５％。结论为硬膜外血肿多伴同部位骨折;在硬膜外血肿中,伴发的脑挫裂伤多位于对冲部位;硬膜下血肿多发生于对冲部位;颅脑损伤后,短期内病变可能会继续发展。 相似文献
4.
5.
A high-temperature x-ray powder diffraction structural refinement indicates that the room-temperature normal spinel, Co2+[Co
2
3+
]O4, transforms to a disordered spinel at temperatures above 1150±30 K, as shown by the decrease of the oxygen u parameter. It is also shown that this transition between normal and disordered spinel is a high order one, where the degree of disordering increases with increasing temperature up to the highest temperature of this study, 1201 K. 相似文献
6.
Clinopyroxenes from rocks 12021, 12037, and 12052 have been studied by electron microprobe and single-crystal X-ray diffraction techniques in order to characterize the crystal-chemical aspects of pyroxene epitaxy and exsolution. The combined chemical and crystallographic data plotted on a Di-Hed-En-Fs data display, based on the unit-cell parameters b and β, suggest a large miscibility gap at low temperature between Ca-rich augite and Ca-poor pigeonites over a large range of Fe/Mg ratios. We also find that in rocks 12021 and 12037 primary pigeonites exsolved augites on both (001) and (100) while primary augites exsolved pigeonite on (001). In rock 12052 the common plane shared by pigeonite cores and epitaxial augite rims is approximately parallel to (100) and little subsolidus exsolution is indicated. 相似文献
7.
A study of the chemical trends displayed by lunar armalcolites has been made in conjunction with single-crystal X-ray structure refinements of lunar and synthetic armalcolite in order to assess the possible importance of Ti3+ in lunar armalcolite and to characterize the effects of cation substitutions on the structure. The apparent cation deficiencies found in lunar armalcolites analyzed with the electron microprobe most likely reflect the presence of Ti3+, although the existence of vacancies cannot be ruled out. Structure refinements of an Apollo 17 armalcolite are consistent with either interpretation. These results support experimental evidence suggesting the presence of Ti3+ in armalcolite and indicate that virtually all lunar armalcolites probably contain ～4–11 mol.% Ti23+Ti4+O5 component in solid solution. The cation distribution in lunar armalcolite is essentially completely ordered. However, synthetic crystals quenched from near 1200°C have been found to retain significant cation disorder. 相似文献
8.
Louise Levien Donald J. Weidner Charles T. Prewitt 《Physics and Chemistry of Minerals》1979,4(2):105-113
The thirteen single-crystal elastic moduli for diopside as determined by the acoustic technique based on Brillouin scattering are: c11=2.23, c22=1.71, c33=2.35, c44=0.74, c55=0.67, c66=0.66, c12=0.77, c13=0.81, c15=0.17, c23=0.57, c25=0.07, c35=0.43, c46=0.073. The Reuss bound of the adiabatic bulk and shear moduli calculated from these data are K s=1.08 Mbar and G=0.651 Mbar. The room-pressure isothermal bulk modulus, K T , and the pressure derivative of the bulk modulus, K′ T have also been determined on a four-circle diffractometer, from a single crystal mounted in a gasketed opposed-anvil diamond cell, giving values of K T =1.13 Mbar and K′ T =4.8. The principal axes of the strain ellipsoid, calculated from the elastic moduli and observed in the static compression data, are identical, and the linear compressibilities are in reasonable agreement. The single-crystal elastic moduli can be correlated with the structural features of diopside. 相似文献
9.
10.